Stereocontrolled Synthesis Of Enantiomerically Pure 2-Dienyl Sulfoxides Via Palladium-Catalyzed Coupling Reactions

Document Type

Article

Publication Date

5-22-1995

Published In

Tetrahedron Letters

Abstract

Enantiopure 2-sulfinyl dienes can be prepared via regio- and stereoselective hydrostannylation of alkynylsulfoxides; after conversion to the corresponding vinyliodides these substrates may be coupled with vinylstannanes via Stille methodology in the presence of BHT.

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