Supramolecular Chirality Transfer To Large Random Aggregates Of Porphyrins

Document Type

Article

Publication Date

6-7-2011

Published In

Chemical Communications

Abstract

Chirality is rapidly induced in a fractal aggregate of the porphyrin t-CuPagg by addition of alpha-helical poly-glutamate. These results demonstrate a facile transfer of chirality via noncovalent interactions to preformed supramolecular assemblies grown in the absence of a chiral template.

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