Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration
Document Type
Article
Publication Date
3-11-2019
Published In
Organometallics
Abstract
An aluminum complex of a tripodal tris(nitroxide)-based ligand has been prepared and characterized. The complex has the ability to participate in metal–ligand cooperative catalysis, which has been exploited for the hydroboration of both aldehydes and ketones. This represents new, transition-metal-like reactivity for an earth-abundant metal.
Recommended Citation
Audra J. Woodside , '19; Mackinsey A. Smith , '19; T. M. Herb; B. C. Manor; P. J. Carroll; Paul R. Rablen; and Christopher R. Graves.
(2019).
"Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration".
Organometallics.
Volume 38,
Issue 5.
1017-1020.
DOI: 10.1021/acs.organomet.8b00933
https://works.swarthmore.edu/fac-chemistry/239