We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a salt metathesis route and was characterized by 1H and 13C NMR spectroscopies, X-ray diffraction, and theory. UV–Vis absorption spectroscopy and electrochemistry were used to access the optical and electrochemical properties of the complex, respectively. Our discussion focuses primarily on a comparison of the gallium complex to the corresponding aluminum derivative and shows that although the complexes are very similar, small differences in the electronic structure of the complexes can be correlated to the identity of the metal.
gallium, redox-active ligand, non-innocent ligand, Lewis acid, Group 13 metals
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Jacob M. Kirsh , '17; Audra J. Woodside , '19; B. C. Manor; P. J. Carroll; Paul R. Rablen; and Christopher R. Graves.
"Synthesis And Characterization Of (pyNO−)2GaCl: A Redox-Active Gallium Complex".