Nonadiabatic Transitions In The Dynamics Of The NeICl Van Der Waals Complex
Chemical Physics Letters
Both electronic energy transfer and vibrational predissociation decay channels are observed following excitation of NeICl complexes to the β ion-pair state. Dispersed fluorescence is detected on the E→X transition as well as the D′→A′ and/or β→A transitions. The vibrational quantum number of the emitting level is reflected in the shape of the Franck-Condon envelope, while its electronic character is determined from the emission wavelength and profile. The relaxation pathways are found to depend on the initial vibrational excitation of the NeICl complex.
Thomas Alex Stephenson, Y. Hong, and M. I. Lester.
"Nonadiabatic Transitions In The Dynamics Of The NeICl Van Der Waals Complex".
Chemical Physics Letters.